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DOI: http://hdl.handle.net/10069/00042019
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高周期15族元素(アンチモンおよびビスマス)-EDTAの構造

##article.authors##

  • 野口, 大介 長崎大学大学院工学研究科教育研究支援部

DOI:

https://doi.org/10.51094/jxiv.206

キーワード:

配位結合、 結晶学、 配位座数、 15族元素、 六座配位子

抄録

ケンブリッジ結晶学データセンター(CCDC)で公開されているデータをもとに、エチレンジアミン四酢酸(EDTA)でキレートされた主要族金属錯体の結晶構造を検索した。ここでは、重15族元素のアンチモン(III)とビスマス(III)のEDTAキレート化合物の結晶構造をまとめた。22種類のSb-EDTA錯体はほとんどが配位数6で配位座数は六座である。47種類のBi-EDTA錯体は、配位数が6から9の範囲であり、ほとんどが配位数8であり、配位座数はすべて六座である。付録では、前回に引き続き、結晶状態の配位数8の水分子が配位したカルシウムおよびバリウム-EDTAアニオンについても概説した。

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公開日時: 2022-11-09 05:38:21 UTC
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