DOI: http://hdl.handle.net/10069/00042018
高周期14族半金属元素-EDTAの結晶構造
－単核錯体から配位高分子まで－
DOI:
https://doi.org/10.51094/jxiv.205キーワード:
錯形成、 結晶学、 ゲルマニウム、 鉛、 金属有機構造体、 多核錯体、 スズ抄録
エチレンジアミン四酢酸（EDTA）の金属キレートは、通常、配位数（CN）が6で、ディスクリートな錯体として表される。一方、EDTAがキレートする重14族元素の陽イオン（重テトレル）は、単量体構造から配位高分子まで様々な結合様式をもつことがX線結晶構造解析から明らかにされてきた。その一部は総説で体系化されているが、重14族元素-EDTA錯体の全体像を明らかにすることはできていない。そこで、3つのGe(IV)-、2つのSn(II)-、5つのSn(IV)-、21個のPb(IV)-EDTA（CN 5-8） の異なる対イオンや（擬）ハロゲンとの重元素テトレル-EDTAキレート錯体の結晶構造を簡単にまとめ、その多様な結合様式を示すことにする。
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引用文献
R. H. Nuttall, D. M. Stalker, Structure and bonding in the metal complexes of ethylenediaminetetraacetic acid, Talanta, Vol. 24, No. 6, pp. 355–360 (1977).
R. L. Davidovich, Stereochemistry of Pb(II) complexes with aminopolycarboxylic ligands. The role of a lone electron pair, Russ. J. Coord. Chem., Vol. 31, No. 7, pp. 455–466 (2005).
野口大介, アルカリ金属-EDTA錯体の配位数と配位座数の多様性, 長崎大学大学院工学研究科研究報告, Vol. 52, No. 99, pp. 22–29 (2022).
野口大介, マグネシウムおよびカルシウムなどのアルカリ土類金属-EDTA錯体の配位数と配位座数, 日本科学教育学会研究会研究報告, Vol. 36, No. 6, pp. 59–64 (2022).
野口大介, 一部にユニークな結晶構造を有するアルミニウムをはじめとする土類金属-EDTA錯体（概論）, 長崎大学大学院工学研究科研究報告, Vol. 52, No. 99, pp. 30–37 (2022).
T. Mizuta, T. Yoshida, K. Miyoshi, A novel structure of spontaneously resolved germanium(IV) complex with ethylenediaminetriacetatemonoacetic acid (Hedta), Inorg. Chim. Acta, Vol. 165, No. 1, pp. 65–71 (1989).
I. I. Seifullina, T. P. Batalova, E. V. Kolchinskii, V. K. Bel’skii, Physicochemical study of germanium(IV) ethylenediaminetetraacetate, Koord. Khim., Vol. 16, No. 6, pp. 773–779 (1990).
E. E. Martsinko, I. I. Seifullina, L. Kh. Minacheva, T. A. Shchur, V. S. Sergienko, Diphenylguanidinium (ethylenediaminetetraacetato)hydroxogermanate hydrate (HDphg)[Ge(OH)(Edta)]·H2O: Synthesis, physicochemical characterization, and crystal structure, Russ. J. Inorg. Chem., Vol. 52, No. 12, pp. 1908–1914 (2007).
V. S. Sergienko, L. K. Minacheva, A. V. Churakov, Specific features of the structure of germanium(IV) complexes with polybasic acids, Russ. J. Inorg. Chem., Vol. 55, No. 13, pp. 2001–2030 (2010).
F. P. van Remoortere, J. J. Flynn, F. P. Boer, P. P. North, The crystal structure of distannous ethylenediaminetetraacetate dihydrate, Inorg. Chem., Vol. 10, No. 7, pp. 1511–1518 (1971a).
K. G. Shields, R. C. Secombe, C. H. L. Kennard, Stereo-chemistry of flexible-chelate–metal complexes. Part III. Crystal structure of dihydrogen ethylenediaminetetra-acetatostannate(II), J. Chem. Soc., Dalton Trans., No. 7, pp. 741–743 (1973).
F. P. van Remoortere, J. J. Flynn, F. P. Boer, The crystal structure of stannic ethylenediaminetetraacetate monohydrate, Inorg. Chem., Vol. 10, No. 10, pp. 2313–2319 (1971b).
C. Brouca-Cabarrecq, B. Marrot, A. Mosset, Crystal structure of aquo (hydroxo) (ethylenediaminetetraacetato) sodium(I) tin(IV), NaSn(OH)(edta)(H2O), J. Chem. Crystallogr., Vol. 26, No. 7, pp. 503–508 (1996).
A. B. Ilyukhin, V. B. Logvinova, R. L. Davidovich, A. L. Poznyak, Crystal structure of stannic ethylenediaminetetraacetates, Russ. J. Inorg. Chem., Vol. 45, No. 8, pp. 1218–1222 (2000).
A. L. Poznyak, A. B. Ilyukhin, Crystal Structure of Ba(Sn(Edta)(OH))Cl.4H2O, Kristallografiya, 1997, Vol. 42, No. 5, pp. 861–862.
Z. Fu, B. Chen, A. He, X. Lv, X. Wei, X. Feng, C. Huang, C. Xia, Y. Jin, The crystal structure of oxonium chlorido-ethylenediaminetetraactetotin(IV) hydrate, C10H17ClN2O10Sn, Z. Krist.-New Cryst. Struct., Vol. 232, No. 6, pp. 941–942 (2017).
P. G. Harrison, A. T. Steel, Lead(II) carboxylate structures, J. Organomet. Chem., Vol. 239, No. 1, pp. 105–113 (1982a).
P. G. Harrison, M. A. Healy, A. T. Steel, EDTA-chelation therapy of lead poisoning: Lead-207 nuclear magnetic resonance and X-ray diffraction studies, Inorg. Chim. Acta, Vol. 67, pp. L15–L16 (1982b).
A. L. Poznyak, G. N. Kupriyanova, I. F. Burshtein, A. B. Ilyukhin, Crystal structure of [Pb(H2Edta)]·1.5H2O, Russ. J. Coord. Chem., Vol. 28, No. 11, pp. 772–774 (1998).
A. B. Ilyukhin, V. B. Logvinova, R. L. Davidovich, Structures of lead(II) nitrilotriacetates and ethylenediaminetetraacetates, Russ. J. Inorg. Chem., Vol. 44, No. 10, pp. 1571–1577 (1999).
T. I. Ivanova, I. V. Rozhdestvenskaya, V. S. Fundamenskii, I. A. Kasatkin, Crystal structure of tetralead hexanitrate ethylenediaminetetraacetatoplumbate(II) tetrahydrate Pb4(NO3)6[PbC10H12O8]·4H2O, J. Struct. Chem., Vol. 43, No. 1, pp. 118–124 (2002).
J. Wang, Z.-R. Liu, X. D. Zhang, W.-G. Jia, D.-M. Fan, Investigation on the syntheses and structures of Pb2+ complexes with EDTA and EDTA derivative ligands, Chin. J. Struct. Chem., Vol. 22, No. 4, pp. 454–458 (2003).
R. L. Davidovich, D. Yu. Popov, A. V. Gerasimenko, V. B. Logvinova, Crystal structure of aminoguanidinium(1+) ethylenediaminetetraacetatoplumbate(II) hemiheptahydrate, Russ. J. Inorg. Chem., Vol. 49, No. 1, pp. 68–74 (2004a).
R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, Crystal structure of (thiosemicarbazide-N,S)lead(II) ethylenediaminetetraacetatoplumbate(II) trihydrate, Russ. J. Inorg. Chem., Vol. 49, No. 3, pp. 395–401 (2004b).
R. L. Davidovich, D. Yu. Popov, A. V. Gerasimenko, V. B. Logvinova, Crystal structures of thiourea(dihydrogenethylenediaminetetraacetato) lead(II) and bisthiourea(dihydrogenethylenediaminetetra acetato) lead(II) monohydrate, Russ. J. Inorg. Chem., Vol. 49, No. 4, pp. 517–522 (2004c).
R. L. Davidovich, A. V. Gerasimenko, V. B. Logvi nova, Synthesis and crystal structure of manganese(II) ethylenediaminetetraacetatoplumbate(II) tetrahydrate, Russ. J. Inorg. Chem., Vol. 49, No. 5, pp. 694–699 (2004d).
A. Ilyukhin, CCDC 743504: Experimental crystal structure determination, CSD Commun., (2009).
D. Zhao, R. H. Zhang, F. F. Li, A new PbII(ethylenediaminetetraacetate) coordination polymer with a two-dimensional layer structure, Crystallogr. Rep., Vol. 61, No. 7, pp. 1077–1080 (2016).
J.-W. Dai, J.-M. Zheng, H.-Y. Li, J.-M. Zhou, X. Dong, Z.-H. Zhou, Halide assisted formation of polymeric eth-ylenediaminetetraacetato lead(II) complexes, New J. Chem., Vol. 41, No. 12, pp. 5198–5204 (2017).
D.-S. Liu, Z.-J. Qiu, X. Fu, Y.-Z. Liu, P. Ding, Y.-X. Zhu, Y. Sui, Synthesis, structures and properties of three lead coordination polymers based on ethylenediaminetetraace-tate ligand, J. Solid State Chem., Vol. 278, p. 120879(8 pp.) (2019a).
D.-S. Liu, Z.-J. Qiu, Y.-L. Xiao, Y.-J. Shen, Q. Zhou, W.-T. Chen, Y. Sui, A novel tetranuclear Pb2+ compound based on ethylenediaminetetraacetate and azide mixed-ligands: Synthesis, structure and properties, J. Solid State Chem., Vol. 279, p. 120952(6 pp.) (2019b).
R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, Crystal structure of ammonium ethylenediaminetetraacetatoplumbate(II), (NH4)2Pb(edta)·3tu·H2O, Russ. J. Inorg. Chem., Vol. 50, No. 10, pp. 1525–1531 (2005).
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