DOI: https://doi.org/10.33609/2708-129X.89.09.2023.14-34
Lanthanoid contraction in chelates of ethylenediaminetetraacetic acid
DOI:
https://doi.org/10.51094/jxiv.560Keywords:
coordination compound, f-block, rare-earth element, polyaminocarboxylic acidAbstract
While lanthanoid contraction has been extensively studied, the knowledge on the complexes of EDTA, a commonly used ligand, remains inadequate. Thus, this study presents a comprehensive analysis based on data from the CCDC. In mononuclear EDTA complexes, systematic lanthanoid contraction depending on their coordination number are obtained. However, in multinuclear or coordination polymer complexes, a greater atomic bond length variation occurs, uncommon for lanthanoid contraction studies in previous research. This suggests the versatility of EDTA as a ligand.
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