DOI: http://hdl.handle.net/10069/00042021
Structural comparison of early first-, second- and third-row main-transition metal-EDTA chelates
Is hexadentately six-coordinated species major?
DOI:
https://doi.org/10.51094/jxiv.212Keywords:
Complex ion, Coordination number, D-block elements, Denticity, X-ray crystallographyAbstract
Crystal structures of early first-row, second-row, and third-row main-transition metal-complexes chelated by ethylenediaminetetraacetic acid (EDTA) are surveyed to clarify whether the well-known hexadentately six-coordinate (6&6) species is major or not. In the early first-row transition metal (Sc, Ti, V, Cr, and Mn)-EDTA, only three of 6&6 species were found within 28 kinds. Whereas there were no such 6&6 species within 50 kinds of the second-row, 15 kinds of the third-row main-transition metal-EDTA. It has been also shown that in the late first-row, there were 31 cases of 6&6 species within 99 kinds by previous study. Therefore, the well-known hexadentately six-coordinate structure is not so much major as minor in the main-transition metal-EDTA complexes from the structural comparison.
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