Lanthanoid contraction in chelates of ethylenediaminetetraacetic acid

Daisuke Noguchi

doi:10.51094/jxiv.560

##article.authors##

Daisuke Noguchi Division of Education and Research Support, Graduate School of Engineering, Nagasaki University https://orcid.org/0000-0003-4449-5538

DOI:

https://doi.org/10.51094/jxiv.560

キーワード:

coordination compound、 f-block、 rare-earth element、 polyaminocarboxylic acid

抄録

While lanthanoid contraction has been extensively studied, the knowledge on the complexes of EDTA, a commonly used ligand, remains inadequate. Thus, this study presents a comprehensive analysis based on data from the CCDC. In mononuclear EDTA complexes, systematic lanthanoid contraction depending on their coordination number are obtained. However, in multinuclear or coordination polymer complexes, a greater atomic bond length variation occurs, uncommon for lanthanoid contraction studies in previous research. This suggests the versatility of EDTA as a ligand.

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I declare that there are no conflicts of interest directly relevant to the contents of this manuscript.

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