プレプリント / バージョン1

高周期15族元素(アンチモンおよびビスマス)-EDTAの構造

##article.authors##

  • 野口, 大介 長崎大学大学院工学研究科教育研究支援部

DOI:

https://doi.org/10.51094/jxiv.206

キーワード:

配位結合、 結晶学、 配位座数、 15族元素、 六座配位子

抄録

ケンブリッジ結晶学データセンター(CCDC)で公開されているデータをもとに、エチレンジアミン四酢酸(EDTA)でキレートされた主要族金属錯体の結晶構造を検索した。ここでは、重15族元素のアンチモン(III)とビスマス(III)のEDTAキレート化合物の結晶構造をまとめた。22種類のSb-EDTA錯体はほとんどが配位数6で配位座数は六座である。47種類のBi-EDTA錯体は、配位数が6から9の範囲であり、ほとんどが配位数8であり、配位座数はすべて六座である。付録では、前回に引き続き、結晶状態の配位数8の水分子が配位したカルシウムおよびバリウム-EDTAアニオンについても概説した。

ダウンロード *前日までの集計結果を表示します

ダウンロード実績データは、公開の翌日以降に作成されます。

引用文献

高木誠(編), ベーシック分析化学, 2006, 化学同人, 260 pp.

村上雅彦, キレート滴定法―各種金属イオンへの適応のための基礎・条件・応用―, 化学と教育, 2015, Vol. 63, No. 5, pp. 246–251.

野口大介, アルカリ金属-EDTA錯体の配位数と配位座数の多様性, 長崎大学大学院工学研究科研究報告, 2022a, Vol. 52, No. 99, pp. 22–29.

野口大介, マグネシウムおよびカルシウムなどのアルカリ土類金属-EDTA錯体の配位数と配位座数, 日本科学教育学会研究会報告, 2022b, Vol. 36, No. 6, pp. 59–64.

野口大介, 一部にユニークな結晶構造を有するアルミニウムをはじめとする土類金属-EDTA錯体(概論), 長崎大学大学院工学研究科研究報告, 2022c, Vol. 52, No. 99, pp. 30–37.

野口大介, 高周期14族半金属元素-EDTAの結晶構造―単核錯体から配位高分子まで―, 長崎大学大学院工学研究科研究報告, 2023a, Vol. 53, No. 100 (準備中).

M. Shimoi, Y. Orita, T. Uehiro, I. Kita, T. Iwamoto, A. Ouchi, Y. Yoshino, The structure of (hydrogen ethylenediaminetetraacetato)antimony(III) dihydrate Sb(C10H13N2O8)·2H2O, Bulletin of the Chemical Society of Japan, 1980, Vol. 53, No. 11, pp. 3189–3194.

V. E. Mistryukov, A. V. Sergeev, Yu. N. Mikhailov, R. N. Shchelokov, Synthesis and crystal structure of (CN3H6)[Sb(Edta)]·2H2O, Koordinatsionnaya Khimiya, 1987, Vol. 13, pp. 1129–1131.

Z. Xie, S. Hu, Crystal structure of sodium ethylenediaminetetraacetatoantimony(III) trihydrate Na[Sb(edta)]·3H2O, Chinese Journal of Structural Chemistry, 1991, Vol. 10, No. 2, pp. 129–131.

B. Marrot, C. Brouca-Cabarrecq, A. Mosset, LiSb(edta)(H2O): A convenient precursor to LiSbS2 and LiSbO3, Journal of Materials Chemistry, 1996, Vol. 6, No. 5, pp. 789–793.

B. Marrot, C. Brouca-Cabarrecq, A. Mosset, [CaSb2(EDTA)2(H2O)8]n: Synthesis, crystal structure, and thermal behavior, Journal of Chemical Crystallography, 1998, Vol. 28, No. 6, pp. 447–452.

H. Fun, S. S. S. Raj, I. A. Razak, A. B. Ilyukhin, R. L. Davidovich, J. Huang, S. Hu, S. W. Ng, Aminoguanidinium (ethylenediamine-N,N,N',N'-tetraacetato)antimonate(III) monohydrate, Acta Crystallographica Section C, 1999, Vol. 55, No. 6, pp. 905–907.

A. B. Ilyukhin, R. L. Davidovich, Effect of a cation on stereochemical activity of lone electron pair in structures of ethylenediaminetetraacetatoantimonates(III), Cat[Sb(Edta)]·xH2O [Cat⁺ = Cs, NMe4, 1/2(H2En), NH4, Tl, K, 1/2Mn, 1/2Cd, or NH3CH2CH2COOH], Crystallography Reports, 1999, Vol. 44, No. 2, pp. 204–213.

A. B. Ilyukhin, A. L. Poznyak, Stereochemical activity of a lone electron pair in antimony(III) and bismuth(III) chelates: Crystal structures of Ca[Sb(Edta)]2⋅8H2O and Ba{[Bi(Edta)]2H2O}⋅H2O, Crystallography Reports, 2000, Vol. 45, No. 1, pp. 56–63.

J. Shen, Q. Jiang, G. Zhong, Y. Jia, K. Yu, Synthesis, crystal structure and thermal decomposition of a novel 3D heterometallic Sb(III)-Pr(III) complex [Sb2-μ4-(EDTA)2Pr(H2O)5]NO3·4H2O, Acta Chimica Sinica, 2007, Vol. 65, No. 16, pp. 1588–1592.

G. Q. Zhong, J. Shen, Q. Y. Jiang, M. J. Chen, Z. P. Zhang, Synthesis, characterization and thermal decomposition of Sbᴵᴵᴵ–M–Sbᴵᴵᴵ type trinuclear complexes of ethylenediamine-N,N,N',N'-tetraacetate (M:Co(II), La(III), Nd(III), Dy(III)), Journal of Thermal Analysis and Calorimetry, 2008, Vol. 92, No. 2, pp. 607–616.

J. Shen, B. Jin, Q. Jiang, G. Zhong, Y. Hu, J. Huo, Synthesis, characterization, and magnetic properties of heterometallic trinuclear complex with Sb(III) and Ho(III), Inorganica Chimica Acta, 2012, Vol. 385, pp. 158–163.

J. Shen, B. Jin, Q. Jiang, G. Zhong, Y. Hu, J. Huo, Edta-linked 5p–4f trinuclear heterometallic complex: Syntheses, X-ray structure and luminescent properties, Journal of Coordination Chemistry, 2012, Vol. 65, No. 17, pp. 3040–3049.

C. López, D. Li, G. Zhong, Synthesis and crystal structure of the bioinorganic complex [Sb(Hedta)]·2H2O, Bioinorganic Chemistry and Applications, 2014, p. 461605.

T. Liu, R. Yang, G. Zhong, Synthesis, structural characterization, and antibacterial activity of novel erbium(III) complex containing antimony, Bioinorganic Chemistry and Applications, 2018, p. 4313197.

L. M. Shkol'nikova, K. D. Suyarov, R. L. Davidovich, V. S. Fundamenskii, N. M. Dyatlova, Structure of bismuth(III) octacoordination comlexonates with ethylene-diamine-N,N,N',N'-tetraacetic acid, Koordinatsionnaya Khimiya, 1991, Vol. 17, No. 2, pp. 253–261.

L. M. Shkol'nikova, M. A. Porai-Koshits, R. L. Davidovich, G. G. Sadikov, Crystal and molecular structure of (ethylenediamine-N,N,N',N'-tetraacetato)(dithiourea)bismuth(III), Koordinatsionnaya Khimiya, 1993, Vol. 19, No. 8, p. 731–735.

L. M. Shkol'nikova, M. A. Porai-Koshits, A. L. Poznyak, Crystal and molecular structures of heptaaquacalcium di[(ethylenediaminetetraacetato) bismuthate (1-)] dihydrate, [Ca(H2O)7][BiEDTA]2·2H2O, Koordinatsionnaya Khimiya, 1993, Vol. 19, No. 9, pp. 634–640.

L. M. Shkol'nikova, M. A. Porai-Koshits, R. L. Davidovich, C. Hu, D. Ksi, Crystal structure of the monoclinic modification of ethylenediamine-N,N,N',N'-tetraacetate(3-) bismuth(III) dihydrate, Koordinatsionnaya Khimiya, 1994, Vol. 20, No. 8, p. 559–562.

S. P. Summers, K. A. Abboud, S. R. Farrah, G. J. Palenik, Syntheses and structures of bismuth(III) complexes with nitrilotriacetic acid, ethylenediaminetetraacetic acid, and diethylenetriaminepentaacetic acid, Inorganic Chemistry, 1994, Vol. 33, No. 1, pp. 88–92.

M. A. Porai-Koshits, A. S. Antsyshkina, L. M. Shkol'nikova, G. G. Sadikov, R. L. Davidovich, Crystal and molecular structure of hexaaquacobalt(II) and hexaaquanickel(II) bis[(μ-ethylenediaminetetraacetate)bismuth(1-)] trihydrates of composition [M(H2O)6][Bi(μ-Edta)]2∙3H2O, Koordinatsionnaya Khimiya, 1995, Vol. 21, No. 4, pp. 295–302.

J. Jaud, B. Marrot, C. Brouca-Cabarrecq, A. Mosset, [Na-Bi(EDTA)(H2O)3]n: Synthesis, crystal structure, and thermal behavior, Journal of Chemical Crystallography, 1997, Vol. 27, No. 2, pp. 109–117.

R. L. Davidovich, A. B. Ilyukhin, S. Hu, Crystal structure of the orthorhombic modification of [Bi(HEdta)]·2H2O, Crystallography Reports, 1998, Vol. 43, No. 4, pp. 605–607.

A. B. Ilyukhin, R. L. Davidovich, V. B. Logvinova, H. Fun, S. S. S. Raj, I. A. Razak, S. Hu, S. W. Ng, Complexes of bismuth(III) with aminopolycarboxylic acids. Crystal structures of guanidinium aqua(ethylenediaminetetraacetato)bismuthate(III) and aminoguanidinium ethylenediaminetetraacetatobismuthate(III), Main Group Metal Chemistry, 1999, Vol. 22, No. 5, pp. 275–282.

A. S. Antsyshkina, G. G. Sadikov, A. L. Poznyak, V. S. Sergienko, Yu. N. Mikhailov, Crystal structures

of [Co(NH3)4(Ox)][Bi(Edta)]⋅3H2O, [Co(NH3)2(Ala)2][Bi(Edta)(H2O)]⋅5H2O, and (CN3H6)[Bi(Edta)(H2O)]: Some aspects of crystal chemistry of bismuth ethylenediaminetetraacetates, Russian Journal of Inorganic Chemistry, 1999, Vol. 44, No. 5, pp. 668–683.

A. L. Poznyak, A. B. Ilyukhin, Crystal structure of [Co(Ox)(NH3)4][Bi(Edta)]⋅3H2O, Crystallography Reports, 2000, Vol. 45, No. 1, pp. 44–45.

V. Stavila, M. Gdanec, S. Shova, Yu. A. Simonov, A. Gulya, J.-P. Vignacourt, Synthesis and structure of {μ-

oxalato-bis[ethylenediaminetetraacetatobismuthato(III)]} pentaamminethiocyanatocobalt(III) dodecahydrate, [Co(NH3)5NCS]2[(Edta)Bi(μ-C2O4)Bi(Edta)]·12H2O, Russian Journal of Inorganic Chemistry, 2000, Vol. 26, No.10, pp. 741–747.

R. L. Davidovich, V. B. Logvinova, A. B. Ilyukhin, Synthesis and crystal structure of β-alaninium ethylenediaminetetraacetatobismuthate(III) monohydrate, Russian Journal of Inorganic Chemistry, 2000, Vol. 45, No. 12, pp. 1822–1826.

R. L. Davidovich, V. B. Logvinova, A. B. Ilyukhin, Ethylenediammonium ethylenediaminetetraacetatobismuthate(III) hexahydrate: Synthesis and crystal structure, Russian Journal of Inorganic Chemistry, 2001, Vol. 46, No. 1, pp. 65–68.

R. L. Davidovich, A. V. Gerasimenko, E. V. Kovaleva, Crystal structure of potassium ethylenediaminetetraacetato bis(thiourea) bismutate(III), Russian Journal of Inorganic Chemistry, 2001, Vol. 46, No. 4, pp. 546–551.

R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, Crystal structure of lithium di(thiourea)ethylenediaminetetraacetatobismuthate(III) hydrate LiBi(Edta)(Tu)2⋅5.5H2O, Russian Journal of Inorganic Chemistry, 2001, Vol. 46, No. 8, pp. 1164–1171.

R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, S. Hu, Synthesis and crystal structure of aminoguanidinium chloro(ethylenediaminetetraacetato)bismuthate(III), Russian Journal of Inorganic Chemistry, 2001, Vol. 46, No. 8, pp. 1172–1177.

R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, Discrete complex anion [Bi(Edta)(H2O)]- of seven-coordinate bismuth: Synthesis and crystal structure of thiosemicarbazidium ethylenediaminetetraacetatobismuthate(III) monohydrate, Russian Journal of Inorganic Chemistry, 2001, Vol. 46, No. 7, pp. 967–972.

R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, Synthesis and crystal structure of lithium ethylenediaminetetraacetatobismuthate(III) tetrahydrate, Russian Journal of Inorganic Chemistry, 2001, Vol. 46, No. 9, pp. 1333–1338.

R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, Synthesis and the crystal structure of cesium ethylenediaminetetraacetobismuthate(III) monohydrate, Russian Journal of Inorganic Chemistry, Vol. 46, No. 10, pp. 1518–1523.

R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, Synthesis and crystal structure of monoprotonated cesium di(ethylenediaminetetraacetato)dibismuthate(III) trihydrate, Russian Journal of Inorganic Chemistry, 2001, Vol. 46, No. 12, pp. 1802–1806.

R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, Crystal structures of rubidium and cesium di (thiourea) ethylenediaminetetraacetatobismuthates(III), Russian Journal of Inorganic Chemistry, 2002, Vol. 47, No. 7, pp. 971–977.

R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, Synthesis and crystal structure of rubidium ethylenediaminetetraacetatobismuthate(III) trihydrate, Russian Journal of Inorganic Chemistry, 2002, Vol. 47, No. 8, pp. 1152–1157.

V. Stavila, A. Gulya, S. Shova, M. Gdanec, Yu. A. Simonov, Synthesis and study of heterometallic Co–Bi compounds based on ethylenediaminetetraacetic acid. Crystal and molecular structures of [Co(DH)2(o-NH2C6H4CH3)2]2[Bi2(μ-Edta)2(H2O)2]·10H2O (DH2 is dimethylglyoxime), Russian Journal of Coordination Chemistry, 2002, Vol. 28, No. 8, pp. 565–572.

R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, Synthesis and crystal structure of aminoguanidinium (thiourea)ethylenediaminetetraacetatobismuthates(III) (CH7N4)[Bi(Edta)(Tu)2]·2.5H2O and (CH7N4)[Bi(Edta)(Tu)(H2O)]·2H2O, Russian Journal of Inorganic Chemistry, 2003, Vol. 48, No. 1, pp. 55–61.

R. L. Davidovich, A. V. Gerasimenko, V. B. Logvinova, The crystal structure of ammonium hydrogenbis(ethylenediaminetetraacetato) dibismuthate(III) dihydrate, Russian Journal of Inorganic Chemistry, 2003, Vol. 48, No. 2, pp. 180–184.

V. Stavila, J. Wignacourt, E. M. Holt, P. Conflant, M. Drache, A. Gulea, Synthesis and structure of some Co(III)–Bi(III) heterometallic complexes: [Co(NH3)5NCS][Bi(EDTA)]2·4H2O, trans-[Co(NH3)4(NO2)2][Bi(EDTA)(H2O)]·2H2O, and [Co(NH3)4(CO3)][Bi(EDTA)]·3H2O, Inorganica Chimica Acta, 2003, Vol. 353, pp. 43–50.

V. Stavila, A. Gulea, N. Popa, S. Shova, A. Merbach, Y. A. Simonov, J. Lipkowski, A novel 3D Nd(III)–Bi(III) coordination polymer generated from EDTA ligand, Inorganic Chemistry Communications, 2004, Vol. 7, No. 5, pp. 634–637.

V. Stavila, A. Gulea, S. Shova, Y. A. Simonov, A. Yurii, P. Petrenko, J. Lipkowski, F. Riblet, L. Helm, An unexpected influence of the nature of the amine on the crystal structure of some Co(III)–Bi(III) heterobimetallic complexes, Inorganica Chimica Acta, 2004, Vol. 357, No. 7, pp. 2060–2068.

Q. Jiang, H. Deng, G. Zhong, P. He, N. Hu, Synthesis, crystal structure and thermal stability of 3D heterometallic Bi(III)-Pr(III) polymer complex, Chemical Journal of Chinese Universities, 2008, Vol. 29, No. 12, pp. 2521–2524.

Q. Jiang, H. Deng, P. He, G. Zhong, K. Yu, Sm(III)-Bi(III) heterometallic complexes with aminopolycarboxylate ligand: Structure, thermal stability and spectral property, Chinese Journal of Chemistry, 2011, Vol. 29, No. 12, pp. 2637–2642.

H. Deng, Q. Jiang, J. Xu, Y. Hu, Synthesis, structure and thermal analysis of Zn(II)-Bi(III) heterometallic complex with ethylenediaminetetraacetate, Advanced Materials Research, 2012, Vols. 554-556, pp. 536–540.

I. Bulimestru, S. Shova, N. Popa, P. Roussel, F. Capet, R.-N. Vannier, N. Djelal, L. Burylo, J.-P. Wignacourt, A. Gulea, K. H. Whitmire, Aminopolycarboxylate bismuth(III)-based heterometallic compounds as single source molecular precursors for Bi4V2O11 and Bi2CuO4 mixed oxides, Chemistry of Materials, 2014, Vol. 26, No. 21, pp. 6092–6103.

C. Teng, H. Xiao, Q. Cai, J. Tang, T. Cai, Q. Deng, Two multifunctional organic-inorganic hybrid complexes based on polyoxometalates, BiEDTA and sodium linker: Crystal structures, photochromic, and catalytic performances, Journal of Coordination Chemistry, 2016, Vol. 69, No.14, pp. 2148–2163.

J. Shen, Q. Jiang, G. Zhong, Synthesis and stereo chemistry of antimony(III) complexes, Progress in Chemistry, 2007, Vol. 19 No. 1, pp. 107–116.

V. Stavila, R. L. Davidovich, A. Gulea, K. H. Whitmire, Bismuth(III) complexes with aminopolycarboxylate and polyaminopolycarboxylate ligands: Chemistry and structure, Coordination Chemistry Reviews, 2006, Vol. 250, pp. 2782–2810.

R. N. Shchelokov, Yu. N. Mikhailov, V. E. Mistryukov, A. V. Sergeev, Ethylenediaminetetraacetatoantimonites and aquaethylenediaminetetraacetatobismuthites: Synthesis and structure, Doklady Chemistry, 1987, Vol. 293, pp. 162–164.

S. Sobanska, J.-P. Wignacourt, P. Conflant, M. Drache, I. Bulimestru, A. Gulea, A new CuBi2O4 precursor: Synthesis, crystal structure and thermal behaviour of Cu(BiEDTA)2, 9H2O, European Journal of Solid State Inorganic Chemistry, 1996, Vol. 33, No. 8, pp. 701–712.

Z. A. Starikova, T. F. Sysoeva, S. S. Makarevich, S. D. Ershova, Crystal and molecular structure of sodium ethylenediamine-N,N,N',N'-tetraacetatobismuth trihydrate, Koordinatsionnaya Khimiya, 1991, Vol. 17, No. 3, pp. 317–321.

B. L. Barnett, V. A. Uchtman, Structural investigations of calcium-binding molecules. 4. Calcium binding to aminocarboxylates. Crystal structures of Ca(CaEDTA)·7H2O and Na(CaNTA), Inorganic Chemistry, 1979, Vol. 18, No. 10, pp. 2674–2678.

M. I. Arriortua, M. Insausti, M. K. Urtiaga, J. Vía, T. Rojo, Synthesis and structure determination of SrCa(edta).5H2O, Acta Crystallographica C, 1992, Vol. 48, No. 5, pp. 779–782.

A. S. Antsyshkina, G. G. Sadikov, A. L. Poznyak, V. S. Sergienko, Crystal structure of the tris(1,10-Phenanthroline)nickel diaqua(ethylenediaminetetraacetato)calciate crystal hydrate [Ni(Phen)3][Ca(Edta)(H2O)2]·10.5H2O, Russian Journal of Inorganic Chemistry, 2002, Vol. 47, No. 1, pp. 39–48.

G. G. Sadikov, A. S. Antsyshkina, V. S. Sergienko, A. L. Poznyak, Crystal structure of the tris(1,10-phenanthroline)nickel diaqua(ethylenediaminetetraacetato)bariate crystal hydrate [Ni(Phen)3][Ba(Edta)(H2O)2]·12H2O, Russian Journal of Inorganic Chemistry, 2002, Vol. 47, No. 1, pp. 49–59.

野口大介, 後期第一系列遷移金属-EDTAキレートの比較構造解析, 長崎大学大学院工学研究科研究報告, 2023b, Vol. 53, No. 100 (準備中).

野口大介, 前期第一・第二・第三系列主遷移金属-EDTAキレートの構造比較:六座・6配位は主要化学種か?, 長崎大学大学院工学研究科研究報告, 2023c, Vol. 53, No. 100 (準備中).

ダウンロード

公開済


投稿日時: 2022-11-04 00:20:02 UTC

公開日時: 2022-11-09 05:38:21 UTC
研究分野
化学