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In-plane Thermoelectric Properties of MXene and poly(3,4-ethylenedioxythiophene)/poly 4-styrenesulfonate (PEDOT/PSS) Hybrid Films

##article.authors##

  • Ishida, Takao Global Zero Emission Research Center, National Institute of Advanced Industrial Science and Technology (AIST)
  • Motoki, Mihoko Global Zero Emission Research Center, National Institute of Advanced Industrial Science and Technology (AIST)
  • Yamamoto, Atsushi Global Zero Emission Research Center, National Institute of Advanced Industrial Science and Technology (AIST)
  • Imasato, Kazuki Global Zero Emission Research Center, National Institute of Advanced Industrial Science and Technology (AIST)
  • Miyata, Masanobu Global Zero Emission Research Center, National Institute of Advanced Industrial Science and Technology (AIST)
  • Ohta, Michihiro Global Zero Emission Research Center, National Institute of Advanced Industrial Science and Technology (AIST)

DOI:

https://doi.org/10.51094/jxiv.1122

キーワード:

Thermoelectric Conversion、 Conducting Polymer、 PEDOT/PSS、 MXene

抄録

We investigated the in-plane thermoelectric properties of hybrid films composed of Ti3C2-MXene and poly(3,4-ethylenedioxythiophene)/poly-4-styrene sulfonate (PEDOT/PSS). The Seebeck coefficient increased as the amount of cleaved MXene in the PEDOT/PSS matrix increased, and the power factor (PF) reached its maximum at a 5% MXene ratio. Furthermore, dimethyl sulfoxide (DMSO) rinse improved the electrical conductivities of the films, and then, a higher PF of 86.8 µW/mK2 was obtained. We evaluated the in-plane thermal conductivities of these hybrid films, to estimate in-plane figure of merit (zT). The highest in-plane zT of the films was 0.019, and this value is twice that of PEDOT/PSS film without MXene.

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公開済


投稿日時: 2025-03-06 01:08:42 UTC

公開日時: 2025-03-06 23:10:11 UTC — 2026-08-21 05:05:11 UTCに更新

バージョン

改版理由

2025年3月にこのサーバーに投稿した初版の再投稿に向けた改定作業中に「導電性高分子PEDOT/PSSとナノ材料MXeneの2成分混合膜」のデータの一部にうっかり「導電性高分子PEDOT/PSSとナノ材料MXene+単層カーボンナノチューブ」の3相系のデータが混合してしまっていた。正確を期すため再度データを確認して「導電性高分子PEDOT/PSSとナノ材料MXeneの2成分混合膜」のみのデータで図面などの修正を行ったものに改版したい。修正したのはFig.4、Table 1, Fig.6とサポーティングのTableS3と関連する本文のごく一部で論文の主旨、結論は変更ない。                                      
研究分野
ナノ・材料科学